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Steam Ejector Vacuum Pumps vs. Dry Mechanical Vacuum Pumps

Learn About Vacuum Pump Options for Steel Degassing

During the early 1900’s the steelmaking industry suffered from poor quality of the final product. This was mainly attributed to the presence of hydrogen and nitrogen in the molten steel. The presence of hydrogen resulted in pinholes and porosity of the final product. The low solubility of hydrogen in steel at ambient temperatures resulted in its release during solidification thereby reducing the yield strength. Similarly, nitrogen also had low solubility in steel which resulted in defects like embrittlement and reduced ductility. These effects laid the foundation of vacuum degassing processing in the steel making industry.

The idea of using a vacuum to remove dissolved gases from molten steel was initially proposed in 1940 by Soviet scientists A. M. Samarin and L.M. Novik. It was first tried industrially in 1952 at the Enakievskii metallurgical plant in the Soviet Union and in 1954 in Germany. By 1960, more efficient vacuum degassing methods such as the Dortmund Hoerder (DH) and Ruhrstahl-Heraeus (RH) methods became popular. They were followed in the mid-1960s by additional processes such as vacuum arc degassing, the ASEA-SKF process, and the vacuum oxygen decarburization process for high chromium steels. Soon after, this technology became an essential part of the steelmaking process and is now used throughout the world [1,2].

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Vacuum degassing systems employ different methods to maximize the surface area of molten steel. Two methods of vacuum degassing: ladle degassing and stream degassing are discussed here.

LADLE DEGASSING

The recent development in ladle steel making by using vacuum arc degassing (VAD), is gaining prominence throughout the world and offers many technical advantages in the melting of high-quality steels. This process is one in which the refining operation, normally carried out in the second stage of the two-slag basic electric arc process, is done in the ladle, and more effectively. Furthermore, the steel is degassed in the same ladle as part of the VAD process.

There are both economic and metallurgical advantages to be gained from the process. The major economic saving is in the reduction of tap-to-tap times since, both the refining and degassing are being done simultaneously in the VAD vessel, a further charge may be melted out in the arc furnace in readiness for subsequent transfer to the VAD unit. The major metallurgical advantages relate to quality and stemming from the high degree of control built into the VAD system [3].

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STREAM DEGASSING

The teaming of forging ingots and ladle-to-ladle degassing take place in a tank which is closed with a vacuum-tight cover. The cover is skewed hydraulically across the tank or is suspended from a cover car and driven over the tank and then lowered. Each cover is equipped for locating the tapping ladle on to a grooved ring made air-tight by the insertion of a Neoprene seal. The ingot or ladle size dictates the dimensions of the vacuum tank. The vacuum tightness between tank and cover is achieved with a sealing ring contained in an open channel. During opening of the cover, the seal is protected from radiation by flooding the channel with water. Both tank and cover flange are water cooled to prevent distortion. The opening for the pouring of the steel is initially covered with a metal membrane so as to allow the evacuation of the tank before teeming. A spray limiter tube is suspended from the cover so as to ensure that the stream is directed into the evacuated tank as intended after melting of the membrane. The diameter and length of the spray limiter tube are calculated to allow the steel to fan out with most of the degassing taking place before the stream exits from the tube. Splashing against the ingot wall or ladle lining is thus prevented. The spray limiter tubes for vacuum-cast forging ingot production consist of special refractory bricks and can be used several times. While those for ladle-to-ladle degassing are made from ceramic material and have an excellent refractory performance with intermediate patching if necessary.

The vacuum tank is refractory lined with firebrick mainly against radiation and possible ladle break-through. Normally, the tank height is such that in case of a ladle break through, the liquid steel content can be contained in the bottom of the tank without affecting the ladle. This makes it possible to remove the empty ladle without difficulties. In the same way the solidified steel can be lifted out by crane. Generally, an ingot mould is used as a ladle stool, which assists in the removal of the cold steel. The underside of the cover is protected by a refractory layer against radiation and splash.

Observation ports in the cover serve to follow the degassing treatment. Local control panels are placed on the cover and are fitted with control valves and instrumentation. Deoxidation and alloying trimming additions can be made during ladle-to-ladle degassing via a vacuum lock. Chemical consistency throughout the melt is one of the results of inert gas stirring.

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VACUUM OXYGEN DECARBURIZATION

VOD Treatment in the Ladle

For the production of low-carbon high-chromium steels, the vacuum ladle degassing station is an ideal facility. An oxidizing variant of this process has been developed, known as the vacuum oxygen decarburizing [VOD] process. In this treatment, not only is the oxygen already dissolved in the melt continually supplemented through the addition of solid oxygen carriers, but gaseous, pure oxygen is also blown onto the melt from above through a lance in order to achieve higher decarburization rates. The VOD process offers the advantages that the decarburization reaction is considerably stronger under low pressure conditions than other oxidizing reactions. This thermodynamic law is of particular interest in the production of very low carbon high-chromium steels.

A modem VOD facility for melt weights of 15 to 90 t comprises the following equipment (Fig 4).

  • Basic lined with a freeboard of 1.0 to 1.5 m porous plug at the bottom for the stirring inert gas supply, slide gate, and refractory lined ladle lid sealed tightly around the ladle rim.
  • Vacuum vessel with ladle support, intemal1y lined, spillage through as a precaution against melt breakouts, vacuum connection, vessel lid fitted with the necessary accessories, and water-cooled splash guard.
  • Top-blowing oxygen lance
  • Probe system for temperature measurement and sampling during the process
  • Vacuum lock for the supply of additions
  • Vacuum pump set (steam jet ejectors, water ring pumps, or Roots pumps) with a suction capacity adequate to maintain pressures substantially below l00 mbar during oxygen blowing to allow for both oxidizing and reducing vacuum treatments to be carried out at pressure below 1 mbar.

The removal of nitrogen

Under vacuum has been the subject of numerous investigations. If there are no strong nitride formers in the melt, the nitrogen content can be reduced to 20 ppm without difficulty. In cases where nitride-forming elements are present in the melt, such as Cr, Va, A1, and Ti, the activity of the nitrogen is appreciably lowered, with the result that nitrogen removal under high vacuum is more difficult. In order to be able to still obtain alloys with low nitrogen contents, low-nitrogen raw materials must be used. Too high a nitrogen content in the Ni-based alloys can lead to microporosity resulting during precision {investment} casting. Production results obtained during melting under vacuum indicates that the nitrogen content is reduced to 50 ppm from an average of 400ppm at the beginning of the treatment. Melting takes place in the open induction furnace which, in contrast to the electric furnace produces substantially higher nitrogen contents. There is still no clear proof that additional argon bubbling has a reducing effect on the nitrogen contents of steel on the other hand, in the cast of Ni-Fe alloys, the influence of argon bubbling as compared with conventional proactive is clearly identifiable with nitrogen contents of up to 50% lower being achieved.

Hydrogen removal

The theoretical equilibria and metallurgical results in this connection have been thoroughly investigated. Hydrogen removal during the degassing treatment here amounts to approximately 85%. Argon bubbling appears to have had no identifiable effect. The inductive bath swirl is fully adequate in the case of this furnace operated at mains frequency.

Vacuum System Selection

There are three types of pumping systems used in vacuum degassing: (a) steam ejectors with necessary condensation stages; (b) steam ejectors in combination with water ring pumps; and (c) dry screw pumps, which don’t require a steam ejector.

All the vacuum pumps need to fulfill the following tasks: Quick pump down, Controlled pump down, maintaning a volumetric flow and reach a low pressure [5].

  • Steam ejector vacuum pumps (SVPs) are mainly used on larger melt sizes up to 350 tonne in integrated steel plants because of the availability of steam. However, the use of dry operating mechanical vacuum pumps (MVPs) for steel degassing has made a tremendous step forward in recent times, but is still confined to melts below 150 tonne.
  • The significant savings in operating costs offered by MVP has created scope for reconsidering the efforts for reducing air leaks, the use of protective gases and minimizing pressure losses between the pump set and the metallurgical reaction vessel.
  • Both systems have made progress in energy optimising but the MVPs have a striking energy advantage, while considering only the overall costs, including those necessary to meet emission constraints and safety standards; Furthermore, the pressure prevailing at the reaction vessel is to be considered when comparing vacuum pumping systems. Also, the means and use of dust abatement systems should be reconsidered since they offer cost savings by reducing the frequency of cleaning, less wear, little sludge handling and significant design suction capacity compared to equivalent SVP.

Table 1: System Design consisting of Roots blower and Dry Vacuum Pumps [4]

VD Melt size [t]Typical VD mass flow rate [kg/hr]Effective pumping speed @0.67 mbar [m³/hr]No of modulesTypical system configuration
No. WH 3rd stageNo. WH 3rd stageNo. DV 1st stage
Example for smaller melts with one system module:
303037,6001522
353543,9001622
404050,1001722
454556,4001822
Example for bigger melts with parallel system modules:
757594,0002722
100100125,3003622
130130163,0003822

 

Table 1 presents the variation of VD mass flow rate and effective pumping speed with increase in melt size. The effective pumping speed shows a significant rise with increase in melt size. Table 2 presents a cost benefit analysis where Dry Mechanical vacuum system results in significant annual savings compared to steam ejector vacuum system [4]. Use of the Dry Mechanical system results in major annual savings. The more number of components will result in higher exergy loss in the MVP system. However, with proper optimization and development of efficient subsystems, these losses can be minimized.

Table 2: Steam Ejector vs Dry Mechanical cost comparison [4]

Degasser type: 45t VD, 8-2-2 system configuration
Heats: 10 heats/day
Utilization: 300 days/year
Annual production: 135,000 t
Type of Vacuum System:Steam EjectorDry Mechanical
Expenses:
Energy and Fluids255,000 ₠4,800 ₠
Maintenance and Spares54,700 ₠8,100 ₠
Total costs per year:309,700 ₠12,900 ₠
Annual Saving296,800 ₠
⩠2.20 ₠/t
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Conclusions

Vacuum Degassing plays an important role in manufacturing high quality steel. The choice between SVP and MVP is based on several aspects like energy and fluid consumption, wear, maintenance and cleaning, redundancy, availability, emissions, dust and sludge handling climatic conditions, safety and health standards. A dry MVP system offers quick response time to gas load changes, pressure control, redundancy, compliance with ATEX requirements, rapid exchangeability of individual pumps and upgrading possibility [5].

References

  • https://vacaero.com/information-resources/vac-aero-training/101401-vacuum-degassing-steel.htm
  • Nueva Mineria y Energia (www.nuevamineria.com)
  • Substech – Substances & Technology (www.substech.com/)
  • http://www.tekservakum.com/wp-content/uploads/2016/11/173_13_02_Steel_Degassing_EN.pdf
  • W. Burgmann, T. Gustsfson, and J. Davene: Selection of vacuum pump system for steel degassing Metall. Res. Technol., 2014, vol. 111, no. 2, pp. 119-128.

About Everest Vacuum & Author:

Everest Vacuum has been providing Technical and R&D solutions for various process industries over the last 15 years. We have provided customized vacuum systems to many reputed organizations in India and overseas. We believe in empowering our customers with the best possible customized vacuum system for eco-friendly overall development.

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Dr V Ravindra is a Mechanical Engineer who has done his PhD from Indian Institute of Technology, Kharagpur. He is working as R&D Manager at Everest Vacuum and he is involved in designing modern vacuum systems for process applications based on customer requirements. He is also developing training modules related to Vacuum Technology and process applications.